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An impurity that can accept an electron from the valence band, leaving a mobile hole. A shallow acceptor creates an impurity level in a crystal near and above the valence-band edge. Donor and acceptor levels are descriptions of appropriate dopants, not universal features of every impurity species.

An impurity that can supply an electron to the conduction band. A shallow donor has a localized occupied impurity level in a crystal near and below the conduction-band edge; thermal or other ionization releases its electron. The binding energy depends on the host dielectric response and effective mass.

For a single impurity level in a crystal with allowed occupations zero and one and equal occupied/empty statistical weights, the Fermi-Dirac distribution givesSince $n_{\mathrm{full}}=N_D{f}_D$ and $n_{\mathrm{empty}}=N_D(1-f_D)$,The same result follows from the two grand canonical ensemble weights $1$ and $e^{-\beta ({ϵ}_D-\mu )}$.

The equal-statistical-weight convention is necessary for the printed formula when $n_{\mathrm{full}}$ and $n_{\mathrm{empty}}$ count whole donor impurities. More generally, donor charge-state degeneracy gives $n_{\mathrm{full}}/n_{\mathrm{empty}}=(g_{\mathrm{full}}/g_{\mathrm{empty}})e^{\beta (\mu -{ϵ}_D)}$. An ordinary singly occupied donor with two spin orientations and a nondegenerate empty state has ratio $2e^{\beta (\mu -{ϵ}_D)}$; at $\mu ={ϵ}_D$ its occupied-to-empty ratio is two, a concrete counterexample to treating the printed expression as universal. The following part uses the paper's ratio-one convention.

The appropriate quantity to minimize is the energy including exchange of particles with the electron reservoir, $\mathcal{E}=E-\mu N$. The occupation of an interacting localized electron level follows fromFor repulsion $U>0$, the first electron costs $ϵ$ and the second costs $ϵ+U$. Comparing all three grand energies givesFor attraction $U<0$, the singly occupied state never minimizes the grand energy. At the crossing of the empty and doubly occupied states, ${\mu }_{\ast }=ϵ+U/2$, its grand energy is $-U/2>0$, while both competing states have zero grand energy. HenceFor $U=0$ the two thresholds coincide at $\mu =ϵ$, giving a direct $0\to 2$ step. At a threshold, distinct occupations are degenerate; zero-temperature minimization alone does not select a unique occupation. A grand canonical ensemble at small positive temperature smooths the steps, withIn particular, the equal-weight empty/pair limit for $U<0$ gives mean occupation one exactly at its crossing; this is not a finite-width singly occupied plateau.