Lennard-Jones potential 2026-10-20
Named after John Lennard-Jones, this is a pair potential energy combining steep short-range repulsion with nonretarded London dispersion force attraction. Its minimum is at , found by differentiation. The power twelve is a convenient model for repulsion, rather than an exact consequence of the Pauli exclusion principle. The power six in the attractive energy follows from second-order coupling of atomic electric dipoles, before retardation matters.