The Johnson--Segalman--Oldroyd model is a linear relaxation-retardation equation made nonlinear through a Gordon--Schowalter objective derivative. Its slip parameter can produce a rate-dependent steady shear viscosity.
In uniaxial extensional flow, the conformation equations give and . Their stress difference gives the displayed extensional viscosity. A stable positive steady conformation requires both denominators positive; a first pole marks loss of a bounded steady response. At zero extension rate the Trouton ratio is three relative to the zero-shear viscosity.
For stress and slip derivative , the steady viscometric functions are , and . Solving the three symmetric xy conformation equations gives , , and .
For nonzero slip parameter with , scale shear rate as and stress as , where . The derivative is and its least value is , attained at . A decreasing homogeneous constitutive segment therefore exists exactly under the displayed condition. It permits different shear rates at the same stress and motivates shear banding; the local curve alone does not select a band-interface stress.
For a tensor , the Gordon--Schowalter derivative used here is
which interpolates among objective convected derivatives as the dimensionless slip parameter changes.
The retardation time controls the delayed strain-rate term in an Oldroyd constitutive equation. Together with the relaxation time it determines the solvent-like high-frequency or high-rate response.
In small-amplitude oscillatory shear,
For Gordon--Schowalter parameter , the steady shear viscosity is
It is shear thinning when .

Articles by others on the same topic (0)

There are currently no matching articles.