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The tensor differential. Use homological grading, so each differential lowers degree by one. The tensor product of chain complexes hasfor $x\in C_p$. This Koszul sign rule givesThus the graded tensor product is a chain complex.

The Hom differential. Write $M_j={\prod }_p{\mathrm{Hom}}_R(C_p,C_{p+j}^{\prime })$. For a degree-$j$ element of this graded Hom complex of chain complexes, use the prescribed differentialThe next application uses degree $j-1$, soIn degree zero, $d_{M}f=f{d}_C-d_{C^{\prime }}f$, so its kernel consists exactly of chain maps. A degree-one element $h$ has $d_{M}h=h{d}_C+d_{C^{\prime }}h$, which is exactly the change between two chain maps related by a chain homotopy. ConsequentlyThis is natural: precomposition and postcomposition by chain maps preserve both degree-zero cycles and degree-zero boundaries.

The dual complex and the sign adjustment. Define the reversed dual chain complexHere $d_X\varphi$ is a functional on $C_{1-i}$, so it belongs to $X_{i-1}$, and $d_X^2=0$. The absence of an additional sign in $d_X$ is intentional.

Interpret finite generation of the free chain complexes as finiteness of their total graded free modules. Then only finitely many degrees occur, and the finite-free evaluation isomorphisms assemble into a graded isomorphismwhere $\varphi \in X_i$, $y\in C_j^{\prime }$, and this component is zero outside $C_{-i}$. The dual module construction and evaluation make $\psi$ natural. Finite rank is needed for evaluation to be an isomorphism; finite total support also makes the sums on the tensor side agree with the products on the Hom functor side.

Under $\psi$, the Hom functor differential has the formThe usual tensor product of chain complexes instead has second coefficient $(-1{)}^i$. SetThis is integer-valued for every $j\in \mathbb{Z}$, including negative $j$, and satisfies $\rho (j)-\rho (j-1)=j-1$. Conjugating the usual tensor differential by $A$ leaves the first term unchanged and changes its second coefficient to $(-1{)}^{i+j-1}$. Hence $d_M=\psi AD{A}^{-1}{\psi }^{-1}$, giving the sign conjugation for the tensor-Hom identificationThis is an isomorphism of chain complexes, not merely of their homology. If one instead assumes only degreewise finite rank with unbounded grading, the ordinary tensor need not identify with the product defining $M$; the finite-total convention is essential to this last conclusion.

We use the James reduced product theorem and the Bott–Samelson theorem: if $X$ is a connected based CW complex with free integral homology, then $JX\to \Omega \Sigma X$ is a weak equivalence, and its induced Pontryagin ring isHere $\Sigma$ is the reduced suspension, $T$ is the tensor algebra, and the multiplication is induced by concatenating James words, hence by concatenating loops. Taking $X=S^{2n}$ supplies a single generator $x$ of degree $2n$, sois free, with one generator in every degree $2nk$ and zero in the other degrees.

The diagonal makes this a homology coalgebra. The generator $x$ is a primitive homology class:There are no nontrivial lower positive degrees in which its reduced diagonal could land. Compatibility of the diagonal with loop multiplication givesThe degree of $x$ is even, so the two tensor factors commute without a Koszul sign rule.

The universal coefficient theorem for cohomology has no Ext terms here because homology is free. Let $a_k$ be the cohomology class dual to $x^k$, with $a_0=1$ and $|a_k|=2nk$. The cup product is dual to the diagonal, henceTherefore the integral cohomology ring is the divided power algebraExplicitly $H^{2nk}=\mathbb{Z}{a}_k$ for $k\ge 0$, and all other cohomology groups vanish. In particular $a_1^k=k!a_k$: over the integers this is not a polynomial ring on $a_1$. This is the integral cohomology of an odd-sphere loop space.

For the requested homology multiplication, use the homology cross product followed by concatenation:The constant loop gives the degree-zero unit. Loop concatenation is associative up to homotopy, which suffices for associativity on homology; Moore loops can make the space-level operation strictly associative. The Künneth theorem identifies the tensor-product homology because its groups are free abelian groups. The Bott–Samelson theorem identifies this product with word multiplication, so $x^i\ast x^j=x^{i+j}$. The Pontryagin ring of an odd-sphere loop space has presentationWith only one generator the tensor algebra has the indicated polynomial presentation. The homology product and the divided-power cohomology product are different operations.