Landau-de Gennes free energy ($f(Q)$)

The Landau-de Gennes free energy is a rotational symmetry preserving Landau free energy of the nematic order parameter. One three-dimensional normalization through fourth order isThe cubic invariant generically produces a first-order phase transition. Its absence in two dimensions is an algebraic identity, not a guarantee that a mean-field approximation captures all fluctuations.

The leading scalar coupling of an electric field to the nematic order parameter is quadratic in the field and linear in the tensor. For uniaxial nematic order, it is $-3\chi \lambda E^2({\cos }^2\vartheta -1/3)/2$. When $\chi \lambda >0$, minimization aligns the nematic director with the field axis and adds $-\chi E^2\lambda$ to the scalar Landau free energy.

For a scalar Landau-de Gennes free energy with $\bar{b}>0$, $\bar{c}<0$, and coupling $-\chi E^2\lambda$ with $\chi >0$, the critical endpoint of a quartic Landau free energy is reached at the displayed field strength and ${\bar{a}}_c=3{\bar{c}}^2/(8\bar{b})$, ${\lambda }_c=-\bar{c}/(4\bar{b})$. It terminates the field-biased first-order phase transition when both field and quadratic coefficient can be tuned. This is a quartic small-field mean-field approximation; higher terms may alter its location.