In the low-temperature regime, the particle rapidly equilibrates near a minimum and only rarely crosses a neighboring maximum. Applying Laplace's method to the exact current formula gives the Kramers escape rates
Each right or left escape changes position by , hence
The reduced continuous-time random walk on minima has off-diagonal transition rates
and diagonal generator entry . Its residence time in each well is exponentially distributed with rate , and the next jump is right with probability .
Put
On , its global maximum is the endpoint , where
and the amplitude has value . The endpoint form of Laplace's method therefore gives
Indeed, with , Taylor expansion gives and ; the scale contributing to the integral is . Outside any fixed neighbourhood of , is bounded above by , so that part is exponentially smaller. This also controls the integrable logarithmic singularity at zero.
Set . Then
The fixed phase
has its unique maximum at , with
The amplitude at the maximum is . The interior-maximum form of Laplace's method gives
Thus
so . This is the Laplace asymptotic for the derivative of the Gamma function.