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For massless up and down quarks, the Quantum chromodynamics kinetic term splits into two independent chirality sectors,The colour covariant derivative acts identically on both flavours and commutes with constant flavour matrices. Independent transformations $q_R\mapsto A{q}_R$, $q_L\mapsto B{q}_L$, with $A,B\in SU(2)$, therefore leave the action invariant. This is chiral symmetry. The non-singlet axial transformations have traceless flavour generators, so they are not broken by the colour axial anomaly; the anomalous axial $U(1)$ is not being included in this symmetry.

For $V_{ij}={\bar{q}}_{Lj}{q}_{Ri}$, transforming each index givesThe nonzero condensate $⟨V⟩=-vI$ is unchanged precisely when $A=B$. Thus chiral symmetry breaking leaves the diagonal vector subgroup $SU(2{)}_V$. Three of the six generators are broken, producing three massless Goldstone bosons in the exact massless limit. They are the pions, represented at low energy by the coset coordinate $U\in SU(2)$.

The uniqueness of the two-derivative two-flavour chiral action follows from the symmetry, rather than merely from guessing an invariant. The chiral group acts transitively on $U$, so every derivative-free invariant is constant. At $U=I$, the stabilizer acts on the three tangent directions by conjugation, the irreducible rotation representation. Its invariant symmetric quadratic form is a single multiple of ${\delta }_{ab}$. Transporting that form around the group gives a unique invariant two-derivative metric. Equivalently, the Maurer-Cartan form $U^{†}{\partial }_{\mu }U$ is traceless, so an independent double-trace term vanishes; the remaining contracted single trace is the same metric. Lorentz invariance supplies the spacetime contraction. Up to total derivatives, a constant term and its overall coefficient, the massless action is thereforeThe positive coefficient is conveniently expressed through the pion decay constant $F$.

Use the Pauli matrices with $\mathrm{tr}({\tau }_a{\tau }_b)=2{\delta }_{ab}$. Expanding the matrix exponential gives ${\partial }_{\mu }U=i{\tau }_a{\partial }_{\mu }{\pi }_a/F+\cdots$. Henceso the three fields have canonical kinetic terms. There is no nonconstant invariant potential in the exact chiral theory, consistent with their masslessness.

For real diagonal $M$, the two terms in the mass trace areTheir sum therefore gives the usual Dirac mass term,These terms explicitly break chiral symmetry. In the low-energy chiral perturbation theory prescription, $V\mapsto -vU$ yieldsThe Pauli matrix algebra implies $(\mathbf{\pi }\cdot \mathbf{\tau }{)}^2=|\mathbf{\pi }{|}^{2}I$. ThusandComparing with the canonically normalized scalar mass term gives the leading pion mass from a two-flavour condensate:Positive quark masses therefore give positive pion squared masses. Even if $m_u\ne m_d$, this leading action depends only on their sum and gives equal masses for all three pions. Strong isospin-breaking effects beyond this order and electromagnetic effects can split them. In the condensate convention used here, $⟨\bar{u}u⟩=⟨\bar{d}d⟩=-2v$, which also explains the factor of two in the mass relation. The massive pions are pseudo-Goldstone bosons, becoming massless as both quark masses tend to zero.