Ginzburg-Landau theory of superconductivity organizes a continuous superconducting transition through a slowly varying complex order parameter. In the simplest isotropic single-component SI model,Here , , changes sign at , and fixes a charge/phase convention. The phenomenological normalization of determines the coefficient values; it should not be confused without qualification with a literal density of independently identifiable pairs.
Microscopic derivation of Ginzburg-Landau theory expands the BCS response near in small gap amplitude and slow spatial gradients. It identifies the complex order parameter with a scaled pair amplitude, supplies the coefficients from the electronic microscopic parameters, and explains the pair charge in the gauge coupling. The agreement is a controlled near-transition limit, not a statement that the truncated local functional remains exact at all temperatures. Lev Gor'kov established this connection explicitly in 1959.[ref]
Microscopic Derivation of the Ginzburg-Landau Equations in the Theory of Superconductivity by Lev Gor'kov. 1959 abstract and derivation: near- reduction and twice-electron charge
Below the transition, minimization gives and condensation-energy density . A variation with respect to givesVariation with respect to gives the supercurrentcoupled to the magnetostatic Ampère law. For nearly uniform amplitude this reduces to London screening and the Meissner effect. The theory supplies two different length scales:The amplitude can vary over the superconducting coherence length, whereas the magnetic field is screened over the London penetration depth.
The surface-energy distinction at explains why type-I and type-II behavior are possible within the same framework. In the type-II regime, quantized winding produces an Abrikosov vortex with a finite core and circulating current. Periodic solutions yield an Abrikosov vortex lattice. Linearization about the normal state gives , while core and field energetics determine the lower entry field. These predictions connect a spatial field theory to measurable vortex patterns and critical fields, beyond a spatially uniform BCS gap equation. Thin-film critical-field observations helped motivate the large- regime; magnetic-decoration experiments subsequently made vortex positions visible.[ref]
Nobel Lecture: Type-II superconductors and the vortex lattice by Alexei Alexeyevich Abrikosov. pp.975–977, film motivation, mixed-state solutions and experimental vortex evidence
These phenomena also enable applications. Type-II conductors support high-field magnets, but flux pinning is needed to limit vortex-motion losses. Phase coherence and fluxoid quantization permit persistent-current loops and interference devices. A weak link supplies Josephson coupling energy, allowing SQUID magnetometry and nonlinear quantum circuits; a junction's detailed current–phase law requires a weak-link model, rather than following automatically from the spatially uniform bulk functional. Microstructure can raise a useful critical current without greatly changing the equilibrium upper field, illustrating the difference between thermodynamic stability and transport performance.
The simple functional has identifiable limits. Far below , the small-gap expansion is uncontrolled; rapidly varying fields can require nonlocal microscopic electrodynamics. Very near a transition in a fluctuating low-dimensional or strongly anisotropic material, mean-field minimization can miss important thermal or quantum fluctuations. Unconventional or multiband pairing can require several order-parameter components and additional gradient couplings. Strong fields can introduce spin-polarization pair breaking omitted by the orbital model. Finally, the static functional predicts equilibrium extrema, not quasiparticle spectra, dissipation, vortex velocities or a unique amplitude-mode frequency without further dynamical input. These are reasons to choose an appropriate extension or a microscopic calculation, not reasons to discard the successful near-transition predictions.