Microscopic derivation of Ginzburg-Landau theory

Expanding the BCS theory near the transition in small pair amplitude and slow spatial gradients produces a local complex order-parameter free energy. The microscopic theory fixes its normalization and coefficients, including the pair's twice-electron charge. This establishes a controlled near-transition relation rather than an exact all-temperature replacement for BCS theory.^[ref]

A pairing-channel Hubbard–Stratonovich transformation replaces an attractive fermion interaction by a complex Cooper pair field coupled to fermion pairs. A Grassmann Gaussian integral then gives a trace-log effective action, with its trace convention fixed to avoid doubling independent spin-pair blocks. The uniform stationary equation is the BCS gap equation. A small-field, slow-gradient expansion near the transition yields Ginzburg-Landau theory of superconductivity; the normalization of the phenomenological field need not equal that of the microscopic gap.

For a clean isotropic three-dimensional weak-coupling s-wave model, use the energy-valued gap $\Delta$, a density of states $N(0)$ per spin, and free-energy density ${\alpha }_{\Delta }|\Delta {|}^2+{\beta }_{\Delta }|\Delta {|}^4/2+K_{\Delta }|D\Delta {|}^2$. Near $T_c$, ${\alpha }_{\Delta }\simeq N(0)(T-T_c)/T_c$. The quartic coefficient follows fromThe integral is $\pi /(2|{\omega }_n{|}^3)$ and the positive odd-integer sum is $7\zeta (3)/8$, yielding the displayed coefficient. The isotropic Fermi-velocity average gives $K_{\Delta }={\beta }_{\Delta }{\hslash }^2{v}_F^2/6$. The pair charge is $q=-2e$ in $D=\nabla -iq\mathbf{A}/\hslash$. These values change under a rescaling of $\Delta$, different density-of-states convention or different material model; the local expansion is a near-transition approximation.^[ref]