Warm-rain pathway: condensation first grows activated droplets, but its relative size growth slows. A sufficiently broad size spectrum creates different fall speeds; large drops collect smaller ones by collision-coalescence. Collection efficiency, turbulence, liquid-water supply and residence time control the bottleneck. Rain reaching the ground also requires survival against subcloud evaporation.
Ice pathway: below freezing, saturation vapour pressure over ice is lower than over supercooled liquid. In mixed-phase air, ice can grow by deposition while droplets evaporate: the Wegener-Bergeron-Findeisen process. Ice also collects droplets by riming and combines by aggregation. Adequate ice nuclei, sustained supersaturation and residence time are critical; particles must become heavy enough to fall, with snow sometimes melting to rain. Condensation or deposition alone is not generally sufficient for rapid precipitation.
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