Write and . Multiplication of the matrix from part (e) givesThese are exactly the constant, difference-frequency, and sum-frequency terms in the PDF, with each Hermitian pair visible. For a weak, slowly varying envelope, the terms at and average out by the rotating-wave approximation. To discard the other transition as well, its detuning must be nonzero and large compared with the drive coupling and envelope bandwidth. Sufficient scale conditions arewhere is a characteristic envelope bandwidth; turn-on transients must satisfy the same spectral restrictions. ThenSmall coupling compared with the optical frequencies alone is not enough for this selective approximation: if is comparable with the pulse bandwidth or Rabi scale, the spectator transition remains driven. A long selective gate also accumulates a small off-resonant Stark phase of order , so that error must be acceptable or compensated. These assumptions distinguish resonant quantum control from an exact decoupling.
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