A reversible Markov chain has a stationary law for which every finite path has the same distribution as its time-reversed path:For a transition matrix , the equivalent detailed balance condition is for all . It implies by summing over . Multiplying the balance identities along a path shows equality of its forward and reverse probabilities when ; conversely, taking paths of length one gives those identities.
For the usual undirected graph with at least two vertices, a simple random walk chooses a neighbor uniformly at each step, so when and are adjacent and zero otherwise, where is the degree of a vertex. The handshaking lemma gives . Thus the stationary distribution of a graph random walk isFor adjacent , , and for nonadjacent pairs both sides vanish. By detailed balance, this is an invariant distribution and the walk started from it is a reversible Markov chain. Connectedness makes the finite walk an irreducible Markov chain, giving uniqueness of its invariant distribution. No aperiodicity assumption is needed for uniqueness, so a bipartite graph is allowed.
If the connected graph has a single isolated vertex, the usual neighbor-choice formula is undefined. With the natural absorbing convention , its unique invariant distribution is and it is reversible. The degree-normalization formula presupposes at least one edge.
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