In the classical experiment, particles whose impact parameter lies between and occupy an incident annulus of area
For a spherically symmetric potential, azimuthal symmetry scatters this annulus into the solid-angle strip
Thus the central-potential classical differential cross-section is
If the relation between and has several branches, one sums this expression over every branch. The corresponding diagram consists of an incoming line offset by from the centre, an outgoing asymptote making angle with the incident direction, and the annulus and solid-angle strip just described.
For quantum scattering by a central potential, the far-field wavefunction is
where is the scattering amplitude. The incident plane wave has probability current
To leading order in , the scattered spherical wave has radial current
The scattered rate through area divided by the incident flux is therefore the quantum differential cross-section from a scattering amplitude:
Write . Since
the outgoing-to-incoming coefficient ratio is . Hence the Partial-wave S-matrix element and scattering phase shift are
The scattering length from a partial-wave S-matrix is
For the stated S-wave scattering solution, as , so
Using the same incoming/outgoing convention,
Therefore
The analytic continuation of has a bound-state pole of the scattering amplitude at in the upper half-plane. Since , this gives
To extract the bound-state wavefunction, multiply the scattering solution by and take the pole limit:
Thus the unnormalized exterior solution is
These data are collected in the Hyperbolic-tangent S-wave exterior solution.

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