Assume zero temperature, complete ionization, constant composition, noninteracting electrons, negligible ion thermal pressure, and Newtonian stellar gravity. Ions supply almost all the mass, while electron degeneracy pressure supplies support. By the Pauli exclusion principle, the two electron spin states fill a momentum sphere up to Fermi momentum . Counting states gives
where is mean molecular weight per electron. The momentum flux of this isotropic Fermi gas is
Writing and performing the integral gives the equation of state of a cold electron gas
In the nonrelativistic limit , , so
In the ultrarelativistic limit , , so
These are polytropic equations of state with indices and , respectively. The relativistic softening underlies the Chandrasekhar mass limit; Coulomb corrections, thermal effects, rotation, and general relativity are excluded from this idealized derivation.
For the nonrelativistic white dwarf, combine the hydrostatic pressure support equation and enclosed mass equation:
Eliminating yields
Introduce the Lane-Emden variables for a stellar polytrope,
The resulting Lane-Emden equation is
The white dwarf surface is at the first zero of , with .
Let be the Lane-Emden surface mass constant. The Lane-Emden mass formula gives
Thus while at fixed composition. Eliminating central mass density gives the polytropic mass-radius relation
More explicitly,
Increasing the mass of a nonrelativistic white dwarf decreases its radius. This scaling ceases to apply when relativistic electron degeneracy pressure becomes important.

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