One quantum state occupies volume in wavevector space. Counting the shell of radius and including spin degeneracy givesUsing gives the stated power with
The Bose-Einstein distribution isPositivity requires not to exceed the ground-state energy, here zero. For a finite system above the condensation limit one has ; it approaches zero from below at Bose-Einstein condensation.
In the continuum limit the number outside the ground state isAt the largest allowed chemical potential, , the integrand behaves near zero as . The integral is finite exactly when . Excess particles must then occupy the ground state, so a Bose-Einstein condensate exists precisely for .
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