In the frame of a planar interface moving at speed , the steady liquid temperature obeys and approaches . ThusThe Stefan condition, with negligible solid-side heat flux, givesso . The kinetic undercooling law then giveswhich requires for advancing solidification.
Scale length with , time with , and temperature with . The base liquid temperature is . For an interface displacement , write the thermal perturbation asThe heat equation givesLinearizing the Stefan condition giveswhile the kinetic law with stabilizing curvature undercooling givesEliminating gives the general implicit dispersion relation
At marginal stability ,and the dispersion relation becomesSince on this curve, the right-hand side is simply . A positive cutoff wavenumber therefore exists exactly whenThe unstable band is , whereA sketch of against the constant shows no crossing above below threshold and one cutoff above it. As , and diverge like , so the range of the morphological instability of a kinetically limited solidification front becomes unbounded.
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