After the real scalar decouples at , its temperature redshifts as . The other particles continue sharing entropy. Just before standard-neutrino decoupling their entropy degrees of freedom areThe temperature of a decoupled relativistic relic therefore obeysA real scalar has one bosonic degree of freedom, whereas one effective neutrino species has energy weight . Hence the contribution of a decoupled real scalar to Neff isHere counts the other particles still coupled to the thermal bath, as specified in the question.
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