For the partition function , differentiation with respect to the external field givesTherefore the magnetization per site is
The mean-field approximation replacesby its first three terms. Since every site has neighbours,The sites then decouple, and their three possible weights sum toHence , , and
Using the field derivative while imposing the self-consistency equation givesAt , is always a solution. Linearizing the right-hand side for small gives slopeA continuous phase transition occurs when this slope crosses one, so, with and ,On the side where the slope exceeds one, the nonzero solutions lower the mean-field free energy and the trivial solution is unstable. The equation has a physical continuous-transition solution only in the corresponding parameter range of this spin-one model.
Landau-Ginzburg theory assumes a local gradient expansion for a slowly varying order parameter. At zero field the microscopic spin-flip symmetry sends , so only even powers occur. Rotational symmetry makes the leading derivative term , while locality and analyticity near the transition organize higher powers and derivatives. Stability requires a positive gradient coefficient and, at an ordinary continuous transition, ; the coefficient changes sign at .
Write , take with , and include the magnetic term . At , minimizing the Landau free energy gives for andfor , so the order-parameter critical exponent is . Substitution gives a singular free-energy density proportional to below , whose second temperature derivative has a finite jump, so the heat-capacity exponent is . Above , the equation gives the magnetic susceptibility , hence . At , , so and .
The Ginzburg criterion compares fluctuations of the order parameter averaged over one correlation volume with the squared mean-field order parameter. The stated correlation function givesMeanwhile , so their ratio scales as . It vanishes at criticality for , grows for , and is marginal at . Thus the ordinary scalar Landau-Ginzburg model has upper critical dimension .
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