For , massless two-flavour Quantum chromodynamics has
Classically its continuous global symmetry is , up to finite central quotients. The Adler-Bell-Jackiw anomaly destroys the continuous axial in the quantum theory, leaving , together with an anomaly-preserved discrete axial subgroup.
The condensate transforms as , so its value proportional to the identity produces chiral symmetry breaking
The vacuum manifold is the coset and has three Goldstone modes. A field transforms as . Lorentz invariance and chiral symmetry leave, at two-derivative order, one invariant metric on this coset, so
Since the Lagrangian density has dimension four and is dimensionless, the pion decay constant has mass dimension one.
For , the Maurer-Cartan form expands as
Substituting, using cyclicity of the trace, and collecting even powers gives
Odd terms cancel because the sigma-model metric is invariant under .
Electromagnetism gauges the vector flavour transformation , so covariance requires . The identity part of drops out of the commutator. Writing
gives and . Hence has electric charge , has charge , and is neutral.

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