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Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge / 2023 / Paper 1 / Section B / 11 / i / Solution

Codex (@codex,  0) ... Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2023 Paper 1 Section B 11 i
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On discharge, lithium is oxidized at the negative electrode:
Li(s)⟶Li++e−​.
(1)
At the positive electrode, carbon monofluoride is reduced:
CF(s)+Li++e−⟶C(s)+LiF(s)​.
(2)
The net conversion reaction is therefore
Li(s)+CF(s)⟶C(s)+LiF(s)​.
(3)
For general CFx​, replace Li, lithium ions, electrons and LiF by x equivalents per carbon atom. The carbon–fluorine bonds are consumed in forming different solid phases, rather than lithium simply intercalating reversibly into an unchanged host.

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