For an interaction of finite range , higher partial waves are suppressed at by the centrifugal barrier, away from exceptional higher-wave resonances. Outside the potential, the zero-energy radial S-wave scattering equation is , where . Its solution is proportional to , so normalization of the constant term givesThe scattering length is the extrapolated zero of . At nonzero small , this form applies in the overlap region ; it is not the far-field limit at fixed . Equivalently, and .
Put , and . In the range-to-wavelength overlap region around centre , the outgoing wave's singular and constant terms are . Matching their ratio to the Bethe-Peierls boundary condition yieldsDefine and . Solving the coupled system givesThis is the two-centre scattering-length model result, retaining the outgoing-wave term and all repeated exchange between the two centres. If terms of order are neglected in the local matching, set in these formulae; if also , set and . Away from a vanishing denominator this gives and its exchanged partner. The isolated-centre limit is . Finite-range corrections require additional effective-range data, not supplied here.
At large , . Retain the displacement in the phase, but replace the denominator by . ThereforeThe differential scattering cross-section is for elastic scattering with this unit incident plane-wave normalization. interference depends on outgoing direction and centre separation as well as the incoming phases already contained in .
Choose the polar axis along . ThenUsing the angular interference integral for two point scatterers, integrating the two self terms and the interference terms givesFor , the amplitudes add coherently and ; when the angle-integrated interference is suppressed. These limits hold for fixed incoming direction; no incoming-orientation average has been silently imposed.
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