Terephthalic acid 2026-11-05
Terephthalic acid is benzene-1,4-dicarboxylic acid, an aromatic dicarboxylic acid with two carboxyl groups attached at opposite positions of a benzene ring. Its neutral molecular formula is . The positions of the groups are part of its identity, not information recoverable from the elemental formula alone.[ref]
The two carboxyl groups make it a useful difunctional building block. Reaction with ethylene glycol, which has two alcohol groups, forms ester connections in polyethylene terephthalate, a polyester. This is step-growth polymerization: growing molecules react through their remaining functional groups.[ref]
Organic Chemistry by John McMurry. Section31.4, Step-Growth Polymers, terephthalic acid and ethylene glycol example
An original repeat-unit bookkeeping calculation isUsing rounded masses, per repeat-unit contribution. The subtraction represents two esterification connections per repeat in the long-chain description; it is not an elementary reaction equation for one isolated pair of monomers forming a complete polymer.
For a finite linear chain assembled from acid molecules and glycol molecules, with no ring closure or side reaction, there are connections. The chain therefore loses water molecules, rather than . End groups supply the difference: its mass is approximately under the same rounded-mass convention.
The molar mass and end-group balance consequently matter alongside conversion. Measuring consumption of acid groups and formation of ester connections tests the reaction model; identifying an aromatic diacid does not determine the final chain length or material properties.