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The original chart has $Z$ vertically and $N$ horizontally. Thus its region (a) is proton-rich relative to the beta-stable band, whereas (b) is neutron-rich.

Electron capture, $e^{-}+(Z,N)\to (Z-1,N+1)+{\nu }_e$, is the other proton-to-neutron weak process; it remains possible for some neutral atoms whose beta-plus decay lacks the $2m_e$ atomic-mass threshold.The emitted alpha particle contains two protons and two neutrons. Very heavy nuclei can also compete through nuclear fission; the chart alone does not determine each nuclide's branching fractions.

The quark transitions are $u\to d+W^{+}$ followed by $W^{+}\to e^{+}{\nu }_e$ in (a), and $d\to u+W^{-}$ followed by $W^{-}\to e^{-}{\bar{\nu }}_e$ in (b). The additional panel shows electron capture as $u+e^{-}\to d+{\nu }_e$ through W boson exchange. The remaining quarks in each nucleon are spectators.

Regions (c) and (d) lie beyond the proton and neutron binding limits, respectively. In (c), unbound protons can be emitted, $(Z,N)\to (Z-1,N)+p$; in (d), unbound neutrons can be emitted, $(Z,N)\to (Z,N-1)+n$. These are the proton drip line and neutron drip line limits, with one- or several-nucleon emission possible according to the nuclear separation energies. They are not merely more distant points on a beta-decay trajectory.

The proton drip line is the proton-rich boundary at which one- or two-proton emission becomes energetically possible. It is governed by proton separation energies, rather than the energetics of beta decay alone.