For an interface perturbation with instantaneous interface kinetics, take the liquid concentration perturbation proportional to . Here is the coefficient of curvature-induced melting-temperature depression. The advection-diffusion equation and interfacial mass conservation giveFor a growing normal mode the unique decaying liquid branch has . Writing , its rate is . Instability requires . The Gibbs-Thomson effect suppresses sufficiently short waves; a quasistatic solute diffusion to solute diffusion changes the rate and must be stated separately.