Over an algebraically closed field, choose a point on the smooth projective curve. The Riemann-Roch theorem gives : the complementary canonical divisor term has negative degree. A nonconstant function in has exactly one simple pole, so it defines a degree-one morphism of algebraic curves to the projective line. A degree-one map between smooth projective curves is an isomorphism. The existence of a rational point is essential over a field which is not algebraically closed.
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