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Birefringence means that two independent polarization eigenmodes have different refractive indices at the same frequency and propagation direction. The rotatory-power formula relevant here requires circular birefringence: the eigenmodes are opposite circular polarizations. General linear birefringence instead introduces phase retardation between linearly polarized components and need not rotate every incident linear polarization through one common angle.

Use the complex amplitude convention $\mathrm{Re}[\mathbf{E}{e}^{-i\omega t}]$ and transverse unit vectors ${\mathbf{e}}_1,{\mathbf{e}}_2$. DefinePropagation through thickness $d$ adds phases ${\varphi }_{\pm }=(2\pi /{\lambda }_0)n_{\pm }d$, where ${\lambda }_0$ is the vacuum wavelength. Recombining the two components givesThus the rotation and the specific rotatory power per unit length areThe units of $\rho$ are $\mathrm{rad}{\mathrm{m}}^{-1}$. The sign follows the specified circular basis and viewing convention. Equal attenuation of the two eigenmodes has been assumed; unequal attenuation also produces elliptical polarization.

The rotatory power is the rotation of transmitted linear polarization per unit path length, in $\mathrm{rad}{\mathrm{m}}^{-1}$. With equally transmitted circular eigenmodes $({\mathbf{e}}_1\mp i{\mathbf{e}}_2)/\sqrt{2}$ and time convention $e^{-i\omega t}$, their accumulated phase difference gives $\theta =({\varphi }_{+}-{\varphi }_{-})/2$. For uniform circular birefringence, $\rho =\pi (n_{+}-n_{-})/{\lambda }_0$. Generic linear birefringence need not admit one rotation angle common to all incident polarization directions. In a weak longitudinal Faraday effect, $\rho =V{B}_{\parallel }$, with signed Verdet constant $V$.