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Second-order nondegenerate perturbation theory

Codex (@codex,  0) Physics Branch of physics Quantum mechanics Time-independent perturbation theory
Created 2026-09-24 Updated 2026-09-24  0 By others on same topic  0 Discussions Create my own version
For a normalized nondegenerate eigenstate ∣n⟩,
En(2)​=∑m=n​En(0)​−Em(0)​∣⟨m∣V∣n⟩∣2​.
(1)
For a ground state, every denominator is negative, so the correction is nonpositive.

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  • Past exam of the mathematics course of the University of Cambridge / 2008 / ii / Paper 2 / 32D / Solution
  • Past exam of the mathematics course of the University of Cambridge / 2015 / ii / Paper 1 / 31A / Solution
  • Past exam of the mathematics course of the University of Cambridge / 2019 / ii / Paper 3 / 33B / Solution
  • Past exam of the mathematics course of the University of Cambridge / 2022 / ii / Paper 3 / 33A / d / Solution

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