Past exam of the chemistry A course of the University of Cambridge 2023 Paper 2 A9 a i Solution 2026-10-20
The stipulated conventional cell is a square of side . Although introduced as a centered rectangular lattice, this equal-side case is a square Bravais lattice viewed with a rotated primitive basis. A corner-to-center separation iswhich is shorter than the separation between adjacent conventional corners. Consequently the first contact of equal circles occurs atThe conventional square represents two lattice points: one from its four shared corners and one from its center. Its packing fraction is thereforeEquivalently, one circle occupies each primitive area . This is square circle packing; the drawing does not define a triangular close-packed lattice.
Past exam of the chemistry A course of the University of Cambridge 2023 Paper 2 A9 b iii Solution 2026-10-20
With the chosen basis, let . The reciprocal lattice conditions giveso . Similarly, and giveAll reciprocal points areThus, in coordinates measured in , the two integer coordinates have the same parity. The reciprocal lattice is another rotated square Bravais lattice, with nearest-neighbor spacing .
