If the relative bead velocity is independent of its separation and has a centered Maxwell-Boltzmann distribution with , averaging the drag dissipation of a bead-spring pair gives the displayed gross loss. The cross term vanishes by the zero conditional mean. At zero velocity gradient, this remains , although mechanical stress power is zero. A thermal bath replenishes microscopic kinetic energy at equilibrium. Equating this gross loss to polymer stress power omits heat-bath input and cannot follow from the independently specified Maxwellian velocity distribution. The overdamped free-energy balance of a Hookean dumbbell uses a probability current velocity instead.

Articles by others on the same topic (0)

There are currently no matching articles.