For a vertical interband transition, the crystal momentum is effectively unchanged because the photon momentum is small. A stimulated downward transition needs an occupied upper state and an empty lower state, with factor ; upward photon absorption has factor . The two matrix elements agree by microscopic reversibility. Their difference is thereforeA common slowly varying transition-strength factor is implicit. Broadening replaces the sharp transition by a convolution; multiple valence bands contribute separate terms.
For one isotropic pair of parabolic energy bands, writeThus . Including the usual twofold spin degeneracy, the number of paired states per volume inside a sphere of radius is . Differentiating with respect to transition energy gives the three-dimensional parabolic interband joint density of statesFor density per angular frequency, . Stating the density convention avoids a missing factor of ; other degeneracies multiply the formula.
At a common carrier temperature, the Fermi-Dirac distribution is a strictly decreasing function of . The direct-gap semiconductor gain condition follows:The lower inequality denotes a transition above the ideal band edge, where the displayed joint density of states is nonzero. Thus quasi-Fermi-level splitting must exceed the transition photon energy. Equality is transparency, rather than net amplification; at zero temperature an allowed transition must also lie within the occupied-electron and empty-valence windows.