Past exam of the physics B course of the University of Cambridge 2012 Paper 1 Section A A1 Solution 2026-10-20
Use absolute thermodynamic temperatures and assume a constant-parameter Arrhenius equation, with composition held fixed so that reaction rate is proportional to the rate constant. Write , where . two-temperature Arrhenius extrapolation eliminates the unknown Arrhenius prefactor and givesConsequentlyA tenfold increase for one interval does not imply another tenfold increase for the next interval: the Arrhenius plot is linear in inverse temperature. Two measured rates alone do not specify a unique extrapolation without a rate law for its temperature dependence; the result above states that modelling assumption explicitly.