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Andrei Sakharov connected the cosmic excess of matter over antimatter with microscopic particle reactions. His 1967 paper proposed baryon number violation and CP violation in the expanding early universe as ingredients for generating a baryon asymmetry. The resulting Sakharov conditions also require departure from thermal equilibrium in the usual reaction-based setting: otherwise inverse reactions and symmetry constraints erase the attempted asymmetry. This turns an astronomical abundance question into a test of particle interactions and cosmological history.^[ref]

The baryon excess requires a mechanism that produces different net baryon numbers from an initially symmetric ensemble. In the usual local, CPT-invariant framework, the Sakharov conditions are baryon-number violation, C and CP violation, and departure from thermal equilibrium. Baryon conservation would preserve zero net baryon number; exact conjugation symmetries equate the conjugate production processes; equilibrium inverse reactions and detailed balance erase a would-be asymmetry. These necessary conditions do not determine its magnitude.^[ref]

For example, let equal numbers of a heavy particle $X$ and its antiparticle decay into channels $i$ with baryon numbers $B_i$. Their mean net yield per pair isIt can be nonzero even though CPT requires equal total widths: the branching fractions differ among channels carrying different baryon numbers. A nonzero decay-rate asymmetry requires interference with both a CP-odd weak phase and an absorptive phase. If the expansion rate overtakes the inverse-reaction rate, decays can occur out of equilibrium; later baryon-violating washout must then be weak enough for the asymmetry to survive.

In electroweak baryogenesis, CP-asymmetric transport near a first-order phase-transition boundary can bias baryon-violating sphaleron transitions. CP violation alone is insufficient: the transition and washout dynamics also matter. In leptogenesis, out-of-equilibrium decays of heavy Majorana neutrinos can generate lepton asymmetry, part of which sphalerons convert into baryon asymmetry while conserving $B-L$. The CKM phase demonstrates CP violation in the Standard Model but does not by itself supply a successful cosmological mechanism. The key quantity is a surviving net charge yield, not merely the existence of a CP-violating reaction.