Spectroscopic wavenumber 2026-10-14
A spectroscopic wavenumber commonly means the reciprocal of the vacuum wavelength of electromagnetic radiation, often in . It is an ordinary spatial frequency, so the vacuum angular wavenumber is . Specify vacuum or in-medium wavelength: the same frequency can have different wavelengths in different media. IUPAC's “wavenumber in medium” entry defines the in-medium reciprocal and notes that unqualified spectroscopic usage often means the vacuum reciprocal.[ref]
For example, a vacuum wavelength of corresponds to . Multiplication by gives . Converting centimetres to metres and converting cycles to radians are separate operations.