WKB quantization condition for a symmetric double well ($\tan \theta =\pm 2e^{\varphi }$)

For a smooth symmetric confining potential energy with four separated simple classical turning points $-x_2<-x_1<x_1<x_2$, defineThe Airy turning-point connection formula applied to a decaying exterior wavefunction gives a central WKB approximation proportional to ${\chi }^{-1/2}[2\cos \theta e^K+\sin \theta e^{-K}]$, where $\chi =\sqrt{2m(V-E)}$ and $K(x)={\hslash }^{-1}{\int }_x^{x_1}\chi dx$. Since ${\chi }^{\prime }(0)=0$ and $2K(0)=\varphi$, the even Neumann boundary condition gives $\tan \theta =2e^{\varphi }$, while the odd Dirichlet boundary condition gives $\tan \theta =-2e^{\varphi }$. For $\varphi \gg 1$, $\theta =(n+\frac{1}{2})\pi \mp \frac{1}{2}{e}^{-\varphi }+O(e^{-3\varphi })$, with the minus correction for even parity. Since ${\theta }^{\prime }=\mathcal{T}/(2\hslash )$ for the single-well classical oscillation period $\mathcal{T}$, the leading double-well tunneling splitting is $2\hslash e^{-\varphi }/\mathcal{T}$.