Incoming links: Fizzle (nuclear explosion)
Gun-type fission weapons don't work with Plutonium-239 because of the presence of Plutonium-240 as an impurity which leads to fizzle.
Good mentions at: youtu.be/dgBDvnqMkT4?t=252
This isotope shows up as an inevitable contaminant in Plutonium-239 for nuclear weapons, because it emits neutrons too fast and makes it harder to assemble the critical mass without fizzle.
It is the presence of this contaminant that made implosion-type fission weapon a necessity: Section "Gun-type fission weapons don't work with plutonium".