Black-body radiation experiment Updated 2025-07-16
Video 1.
Black-body Radiation Experiment by sciencesolution (2008)
Source. A modern version of the experiment with a PASCO scientific EX-9920 setup.
Bohr model Updated 2025-07-16
Was the first model to explain the Balmer series, notably linking atomic spectra to the Planck constant and therefore to other initial quantum mechanical observations.
This was one of the first major models that just said:
I give up, I can't tie this to classical physics in any way, let's just roll with it, OK?
It still treats electrons as little points spinning around the nucleus, but it makes the non-classical postulate that only certain angular momentums (and therefore energies) are allowed.
If something does a quantum jump, what causes it to decide doing so at a particular time and not another? It is expected that a continuous cause would have continuous effects.
This concern was raised immediately by Rutherford while reviewing the Bohr model in 1913 as mentioned in The Quantum Story by Jim Baggott (2011) page 32.
Planck's law Updated 2025-07-16
Used to explain the black-body radiation experiment.
The Quantum Story by Jim Baggott (2011) page 9 mentions that Planck apparently immediately recognized that Planck constant was a new fundamental physical constant, and could have potential applications in the definition of the system of units (TODO where was that published):
Planck wrote that the constants offered: 'the possibility of establishing units of length, mass, time and temperature which are independent of specific bodies or materials and which necessarily maintain their meaning for all time and for all civilizations, even those which are extraterrestrial and nonhuman, constants which therefore can be called "fundamental physical units of measurement".'
This was a visionary insight, and was finally realized in the 2019 redefinition of the SI base units.
Video 1.
Quantum Mechanics 2 - Photons by ViaScience (2012)
Source. Contains a good explanation of how discretization + energy increases with frequency explains the black-body radiation experiment curve: you need more and more energy for small wavelengths, each time higher above the average energy available.
Quantum number Updated 2025-07-16
However, it very cool that they are actually discovered before the Schrödinger equation, and are present in the Bohr model (principal quantum number) and the Bohr-Sommerfeld model (azimuthal quantum number and magnetic quantum number) of the atom. This must be because they observed direct effects of those numbers in some experiments. TODO which experiments.
E.g. The Quantum Story by Jim Baggott (2011) page 34 mentions:
As the various lines in the spectrum were identified with different quantum jumps between different orbits, it was soon discovered that not all the possible jumps were appearing. Some lines were missing. For some reason certain jumps were forbidden. An elaborate scheme of ‘selection rules’ was established by Bohr and Sommerfeld to account for those jumps that were allowed and those that were forbidden.
This refers to forbidden mechanism. TODO concrete example, ideally the first one to be noticed. How can you notice this if the energy depends only on the principal quantum number?
Video 1.
Quantum Numbers, Atomic Orbitals, and Electron configurations by Professor Dave Explains (2015)
Source. He does not say the key words "Eigenvalues of the Schrödinger equation" (Which solve it), but the summary of results is good enough.