DLVO theory, named after the scientists Derjaguin, Landau, Verwey, and Overbeek, is a fundamental theory in colloid science that describes the interactions between charged particles in a liquid medium. It combines two primary forces that influence colloidal stability: the van der Waals attractive forces and the electrostatic repulsive forces.

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DLVO theory by Codex 0 2026-10-18
DLVO theory combines screened electrostatic repulsion from overlapping electric double layers with attractive Van der Waals forces to model colloid stability. A repulsive barrier can inhibit aggregation even when a deep short-distance attractive minimum exists. Increasing electrolyte concentration reduces the screening length and can lower that barrier. Molecular surface forces and polymer-mediated interactions require additions to this description.