The photoelectric effect is a phenomenon in which electrons are emitted from a material (typically a metal) when it is exposed to electromagnetic radiation, such as light. The effect was first observed by Heinrich Hertz in 1887 and was later explained by Albert Einstein in 1905, which contributed to the development of quantum theory.
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The photoelectric effect is the release of electrons from matter following photon absorption. Here the focus is emission from a metal surface into vacuum: a photon supplies energy, the work function pays the escape cost, and the remainder can become the emitted electron's kinetic energy. A photocurrent counts collected electric charge; a stopping potential probes the upper kinetic energy limit. These are different measurements.
In 1905, Albert Einstein proposed that an individual light quantum could transfer its whole energy to one electron. His §8 allowed losses before escape, distinguished the fastest emitted electrons from the rest, and predicted a straight stopping potential versus frequency relation with a material-independent slope. He separately predicted that changing light intensity changes the number emitted without changing their velocity distribution under otherwise identical conditions. He also discussed incomplete transfer and limits to the account.[ref]
On a Heuristic Point of View Concerning the Production and Transformation of Light by Albert Einstein. Einstein's Miraculous Year; §8, printed pp. 193–196; full 21-page English translation of the 1905 paper
The useful modern starting model is a clean, homogeneous metal with independent single-photon events, negligible initial thermal broadening, negligible lowering of the surface barrier by an applied electric field, and negligible electric fields from the emitted electrons themselves. Specify the surface and its work function; it is not enough to name the bulk material. The Einstein photoelectric equation describes the upper edge of the emission energy distribution. It neither predicts that every absorbed photon liberates an electron nor supplies the whole photocurrent curve. Its appeal is that a complicated surface process still exposes the universal Planck constant through a simple slope.
No matter how hight the wave intensity, if it the frequency is small, no photons are removed from the material.
This is different from classic waves where energy is proportional to intensity, and coherent with the existence of photons and the Planck-Einstein relation.