The quantum harmonic oscillator is a fundamental concept in quantum mechanics that describes the behavior of a particle subject to a restoring force that is proportional to its displacement from an equilibrium position. This model is essential for understanding various physical systems, such as vibrations in molecules, phonons in solid-state physics, and quantum field theory. Here's a detailed overview of the quantum harmonic oscillator: ### 1.
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The quantum harmonic oscillator describes a particle of mass in a quadratic potential energy with angular frequency . In the position representation its Quantum Hamiltonian isThe model is useful far beyond a literal spring: a Taylor series about a stable equilibrium with positive potential curvature has this quadratic term as its leading nonconstant approximation. The pure quartic oscillator has zero curvature at its minimum, so that particular approximation does not apply. [ref].
In units with , creation and annihilation operators giveHere is the number operator. Restoring the reduced Planck constant, the energy eigenvalues are for : neighboring levels are separated by , and the ground-state energy is the zero-point energy .
With length scale and dimensionless coordinate , the ground state is the normalized Gaussian wave packetFor , this is precisely the trial wavefunction in the quantum variational principle. The balance of kinetic energy and potential energy therefore recovers the exact ground-state energy using only Gaussian integrals.
We get the time-independent Schrödinger equation by substituting this into Equation "time-independent Schrödinger equation for a one dimensional particle":
Now, there are two ways to go about this.
The first is the stupid "here's a guess" + "hey this family of solutions forms a complete basis"! This is exactly how we solved the problem at Section "Solving partial differential equations with the Fourier series", except that now the complete basis are the Hermite functions.
The second is the much celebrated ladder operator method.