Diagonal electric-dipole matrix elements and parity

ID: diagonal-electric-dipole-matrix-elements-and-parity

A parity eigenstate has zero expectation of an odd coordinate, hence no diagonal electric-dipole coupling to a uniform oscillatory field. Stationarity alone does not prove this: an oscillator displaced by has . Degenerate subspaces or a parity-breaking static field require a separate symmetry analysis.

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