Diffusion-capacitance analogy
ID: diffusion-capacitance-analogy
A quasi-static chemical potential outside a fixed-shape droplet solves the same Laplace equation as an electrostatic potential outside an equipotential conductor. If on the droplet and zero on the surrounding reservoirs, its outward diffusive current iswhere is the corresponding electrostatic capacitance in a medium of permittivity . The arbitrary cancels against the capacitance's proportionality to . Thus electrostatic geometry directly determines evaporation rates.
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