Entropy excess of a van der Waals gas
ID: entropy-excess-of-a-van-der-waals-gas
For one mole with temperature-independent parameters , the equation of state is . A Maxwell relation gives , so the volume dependence is . Matching the ideal gas entropy at infinite volume fixes the excess at the same to . The attraction contributes to the Helmholtz free energy but no excess entropy when is independent of temperature. A temperature-dependent attraction parameter would change this conclusion.
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