 Equality in Boole's inequality

For finitely many events, or a countable family with finite sum of individual probabilities, equality in the uncapped union bound holds exactly when every pairwise intersection has probability zero. Equivalently, at most one event occurs almost surely. Pairwise disjoint events give equality, but literal disjointness is stronger than necessary: shared outcomes of probability zero do not change either side. For the capped bound, if the sum exceeds one, equality instead means that the union is an almost sure event; overlap can then have positive probability.

The cap and the disjoint case are both sharp. If the individual probabilities sum to at most one, put the events on separate pieces of a sample space to attain their sum. The twelve-outcome disjoint example does this with two events of probability $1/3$. If the sum exceeds one, a covering union can attain the cap: on the same twelve-outcome sample space, $A=\{1,\dots ,8\}$ and $B=\{5,\dots ,12\}$ have sum $4/3$ and exact union probability one. These are sharpness examples, not an assertion that every overlapping family attains the bound. Positive-probability disjoint events are also not independent events, because their joint probability is zero while the product of their individual probabilities is positive.