Integrating the Crooks fluctuation theorem over work and using normalization of the reverse probability distribution givesConsequently Jensen's inequality gives . Some realizations may nevertheless have . This is a work relation with equilibrium endpoint preparations, while the integral fluctuation theorem for total entropy production uses the actual final forward distribution. [ref]
The Entropy Production Fluctuation Theorem and the Nonequilibrium Work Relation for Free Energy Differences by Gavin E. Crooks. Crooks, 1999, Eq. (3) and derivation from Eqs. (10)–(11)
Jarzynski equality is a result in statistical mechanics that provides a relationship between the work done on a system during a non-equilibrium process and the change in free energy of the system. It was formulated by Christopher Jarzynski in 1997.
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