 Solution

True thermal equilibrium requires a thermal ionizing radiation field as well as chemical balance; equality of photoionization and recombination rates alone would require a specified external radiation field. Under the stronger equilibrium assumption, apply the Saha equation to pure hydrogen. The electron spin factor cancels the ground-state electronic degeneracy, givingAt $T=10^4\mathrm{K}$, $k_{B}T=0.862\mathrm{eV}$ and $S=3.38\times 10^{20}{\mathrm{m}}^{-3}$. Charge neutrality gives $n_e=n_p$. Importantly, the known quantity from d is the neutral number density, not the total number density; use Saha neutral fraction from a measured neutral density to obtain $n_p=\sqrt{S{n}_{\mathrm{HI}}}=5.31\times 10^7{\mathrm{m}}^{-3}$. ThereforeThis extraordinarily small neutral fraction is the result of applying thermal equilibrium to dilute intergalactic gas; it is not a realistic inference from photoionization equilibrium with a nonthermal cosmic background. For the axial geometry of d, the equilibrium neutral fraction is smaller by $\sqrt{20}$.