Photoionization equilibrium

Photoionization equilibrium holds when the local or integrated photoionization rate equals the radiative recombination rate, so the ionized fraction is stationary.

An ionization-bounded nebula contains enough absorbing material to trap the relevant ionizing photons, unlike a density-bounded region that ends before its ionization front. In dust-free hydrogen at steady photoionization equilibrium, the absorbed stellar photon rate equals the integrated Case B recombination rate. Escape, absorption by dust, and competition from other species must be accounted for before identifying the absorbed hydrogen rate with the entire stellar ionizing luminosity.

For fully ionized pure hydrogen of density $n(r)=n_0(r/r_0{)}^{-\beta }$ and constant Case B recombination coefficient $\alpha$, the total recombination rate isThe central integral converges only for $\beta <3/2$; an envelope extending to infinity has finite recombination capacity only for $\beta >3/2$. At $\beta =3/2$, each logarithmic radius interval contributes equally. A cored power-law density profile removes the central singularity.

For the cored power-law density profile that is constant inside $r_c$ and falls as $r^{-\beta }$ outside, with $\beta >3/2$, the maximum integrated Case B recombination rate isA hydrogen-ionizing photon production rate greater than this has no finite radius at photoionization equilibrium. Equality requires an infinite ionized radius. Other core shapes change the coefficient but retain the convergence condition $\beta >3/2$.

The recombination time is the characteristic time for an ionized plasma to recombine after its ionizing source is removed. Uniform hydrogen with electron density $n_e$ and recombination coefficient $\alpha$ has $t_{\mathrm{rec}}=1/(\alpha n_e)$.

Case B recombination excludes direct recombinations to the ground state because their ionizing photons are assumed to be absorbed locally. The coefficient ${\alpha }_B$ therefore counts recombinations to excited states.