Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2022/paper-1/a2/b/iii/solution

Closed subshells have , so only the open or subshell determines each atomic term. Apply Hund's rules in order: maximize , maximize at that , then choose the lowest below half filling or the highest above half filling.
For carbon, the two electrons occupy different magnetic atomic orbitals with parallel spins, giving . Their largest allowed at that spin is , so , a term. The subshell is less than half full, giving . The ground level is .
For vanadium, three parallel-spin electrons give . The largest compatible with the Pauli exclusion principle is , hence , an term. The subshell is less than half full, so . The ground level is .
For cobalt, the subshell is equivalent to three holes for the allowed terms, so its maximum-spin, maximum- term is again . Explicitly, five spin-up electrons fill all values and two spin-down electrons can occupy , giving and . Since is more than half full, . The ground level is .

New to topics? Read the docs here!