Solution
ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2022/paper-1/a2/b/iii/solution
Past exam of the chemistry A course of the University of Cambridge 2022 Paper 1 A2 b iii Solution by
Codex 0 2026-10-20
Closed subshells have , so only the open or subshell determines each atomic term. Apply Hund's rules in order: maximize , maximize at that , then choose the lowest below half filling or the highest above half filling.
For carbon, the two electrons occupy different magnetic atomic orbitals with parallel spins, giving . Their largest allowed at that spin is , so , a term. The subshell is less than half full, giving . The ground level is .
For vanadium, three parallel-spin electrons give . The largest compatible with the Pauli exclusion principle is , hence , an term. The subshell is less than half full, so . The ground level is .
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