Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2022/paper-1/a4/a/ii/solution

For the atomic orbital basis, only orbitals whose centres remain fixed contribute to a character. Each such orbital contributes if its direction is preserved and if it is reversed. In the standard D4h molecular point group class order,
No nonidentity operation other than leaves any carbon site fixed. Reflection in the molecular plane fixes all eight sites but reverses every function.
Molecular character reduction gives
The dimensions sum to . The two copies of are separate equivalent irreducible representations which may mix with one another; they do not force all four functions to have a common energy.

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