Solution
ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2025/paper-1/a3/a/i/solution
Past exam of the chemistry A course of the University of Cambridge 2025 Paper 1 A3 a i Solution by
Codex 0 2026-10-20
For one normal mode, the fundamental is , with other modes initially in their ground levels. In the linear-dipole harmonic approximation, the transition moment is nonzero for , so a vibrational fundamental is normally much stronger than its overtones, provided the mode has vibrational infrared activity.
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