Solution
ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2025/paper-2/a9/f/solution
Past exam of the chemistry A course of the University of Cambridge 2025 Paper 2 A9 f Solution by
Codex 0 2026-10-20
Lattice vibrations contribute a phonon heat capacity. At temperatures well below the Debye temperature, its leading contribution is proportional to , whereas the electronic part is proportional to :The lattice term can therefore become important rapidly as temperature rises, even if the electronic term dominates sufficiently close to zero. At higher temperature the lattice contribution approaches the Dulong-Petit law value per mole of atoms within the harmonic approximation. This is not a claim that the low-temperature law holds at all temperatures.
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